Friday 6 April 2012

the FAT and the LIPID:Le Terminology

The FAT and the LIPID: Le Terminology                                                      

Le intermission,

Before we delves more into the realm of fat and lipid, there are certain terms that you should know. People in the food industry used this term very much. Even those whom had worked as a frier in a fast food restaurant can recognized these term. (KFC worker should recognize some of these term)

Note that, all of these term are related to the type of  fatty acids present in the Triglycerides (TAG), their location (middle? end? remember, TAG is consist of 3 fatty acid), chain length of the fatty acid and many more(I wrote the only one I've touched in previous post, there many more characteristic that affect all of these term) So, enough chat and let's get started shall we?


MELTING POINT
Fat and oil had melting point? Well, in this case, only fats are involve; saturated fats are solid in room temperature, like butter and margarine. It usually covers a wide range of temperature and the point where the fat melts. Let's take an example, suppose there are 2 butter; brand A & B. A melts at 30'C but B at 40'C, the different in melting point still exist even they are the same thing. The reason is because both butter have different composition of TAG. Among the fatty acids, the melting point increases with chain length. So, if the the type of TAG consists of 3 Arachidic acid (C20), and the other TAG consist of 3 Palmitic acid (C16); the butter with 3 Arachidic acid will have higher melting point.

SPECIFIC HEAT
if you study science, I'm sure you're know this. It is defined as the quantity of heat (yes, heat can be measured, Let's just say, it is measured in terms of Joules, where the energy is almost equivalent to the watt in electricity appliance, (joule=organic, watt=inorganic) If you want to know how, I suggest you've study thermodynamics in physics)  required for a 1'C to increase in a unit weight of fat. In layman term; the energy needed to increase heat by 1'C. for most fatty acid, the specific heat depend on the unsaturation of it chain. The more unsaturated the fat/oil, the higher the specific heat . So in this case, the specific acid of oil is higher than fat. To make it sound simple, it easier to fry a butter than to heat an  cooking oil.

SMOKE POINT
it is the temperature point where the fat/oil started to produce smoke ( just like it's name). Well you can see this if you continuously use the same cooking oil.Let say, you use the same oil to fried 70 chicken. However, after certain time, the oil started to produce smoked. if you could find a thermometer (I'm just kidding, you can't use thermometer, the mercury will instantly fly of the roof; It's very hot) the temperature recorded is the smoke point. In other meaning, you should change the oil. The oil which had reached smoke point is hazardrous. This because certain change had occur in the composition of oil, where there is bound that certain Acrylamide (A carcinogenic (cancer inducing) substance) had formed. If you want cancer in several years, by all mean, continue the cooking. :)

FLASH POINT
It is the temperature where the fat/oil can ignited a fire. Well, yes, oil can ignite fire IF YOU PUT A FIRE IN IT! as in this case, by HEATING (not put fire on it) to certain temperature, the oil can start a fire by itself. So if you want to produce Acrylamide, better watch out for Flash point, or all your work are in vain :)

CLOUD POINT
It is the temperature at which the fat/oil (mostly oil) turn cloudy. The cloudy in this case meant the start of crystallization of liquid fat/oil. In Malaysia, once done cooking, just leave the pan as it is. by 1 day, I believe the oil should have solidified and had a cloudy colour on it. Well, for those living in a cool climate, I dunno. But I guess you see these more than we (those who live in a tropical climate ) do.

 POLYMORPHISM
It is defined as the existence of a substance in 2 or more form. The differences between form arise due to many form of molecular packing in a crystal structure. Like I said in the previous post (or have I?), the fat/oil does not only consist of 1 type of TAG. It consists of several TAG which have different type of fatty acid attached to them. To make matter worse, A TAG with same type of fatty acid attached but different arrangement DOES NOT COUNT AS THE SAME TAG. So, what use is polymorphism anyway? well, in analyzing a fat/oil, the reading could give many melting point (If you use Differential Scanning Calorimetry (DSC) you understand this) The many melting point is due to these TAG will did turn crystal (solidify) but each structure is not the same as the other. Thus, these crystal will had their own melting point and when analyze it give the number of melting point correspond to the number of tag it had. Just like that. :)

So, these are the term you should know. there are actually more term, there are even that I didn't know. However, the answer is the same, if you want to know more, please look it on the web. :)

This is for now, see you in chapter 2. :)

I'ts getting harder to post in blog nowadays, however I insist on continuing it. Please check the blog on weekends, as I will most probably post at these time. Thank you for reading and please subscribe!

Adieu.

                                                                                                                                                         

Friday 30 March 2012




The Carbohydrate Syndicate


Le chapter1: It begin with a sweet smile...

Almost ANYTHING has carbohydrate. Almost everyone know what is carbohydrate. But depending on whom you're talking to, the answer may differ. Well, I bet most every person that you ask will have the main idea of carbohydrate as a nutrient in their explanation. Well, that's correct, but you need to know more than that. There's more to carbohydrate than just a nutrient. The secret must be revealed. Now, I will tell you about the Carbohydrate Syndicate.

Well, to begin with, let's start with basic. Carbohydrate started with 3 elements of periodic table combined in a ratio. Those element will be Carbon (C), Hydrogen (H) and Oxygen (O) which combined in a ratio of 1:2:1. The most basic carbohydrate is C6:H12:C6 or C6H12O6. If you're a chemist, or biologist, you will know that this is the chemical formula for Sugar. But to most people in the world, when they say sugar, they would visualize the normal sugar, the table sugar. (The sugar that shape like a small glittering crystal, that 3 years old kid will mistaken sand for it). Well, my fellow readers, that's is Sucrose.

The Sucrose'c chemical formula is C12H22O11. "But you've said that it was C6H12O6!" said SOME of my readers. Well that's true, the true story is that the sugar (table sugar) is not the basic Carbohydrate. The most basic Carbohydrate is a Glucose. And Glucose is the one running the show in the Carbohydrate Syndicate.

In the Carbohydrate Syndicate, there is some sort of strata where it was categorize based on how many carbohydrate it had. Let's start with lowest form, the simple sugar (ok, from now on, any sugar I said does not refer to the table sugar). The simple sugar, is also known as Monosaccharide. In latin, (Mono = single, Saccharide = Sugar) There were 3, Glucose, Galactose and Fructose. 
                                                                                 
 The structure formula for all 3 were C6H12O6. Although same chemical formula, it differ in arrangement as you can see in the wrongly spelled picture (Monaosaccharides, that's internet for you). These 3 can combine together to make a new sugar, where it is categorized as Disaccharide. But at a price, all combination must have a Glucose. The Sucrose is in this group. The combination is as follow:

Galactose + Glucose = Lactose
Glucose + Glucose    = Maltose
Fructose + Glucose   = Sucrose

Well, if you're an astute reader, you will realized that sucrose is C12H22O11, and it was made from 2 compound of C6H12O6. There is something missing here. Even in chemical reaction, the mother nature does not make it simple. There must be something lost in a reaction. As in this case, a molecule of water is formed, to balance the equation or so it seems..   See the picture:

    Well, if you do some homework, you will find that the Lactose and Maltose are also formed like this.

That's 2 strata, and we haven't touched the fun part yet, the part that you will know their real name. YES, the name (Maltose, Lactose, etc.) is not their real name. It's just a cover up name.  Well, ....


...This is THE Carbohydrate Syndicate.  







 That's it for now for the introduction of Carbohydrate Syndicate. We're going to the deeper end soon....

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Cheers!



Preview for le Chapter 3: True Colors
The reaL NAME for the Sucrose is 2-a-D-Glucopyranosyl-b-D-Fructofuranoside


                                                     To Be Continued...